W
hen covalent bonds are broken and reformed,a polyatomic ion may rearrange to monatomic Cation.

Permanganate Changes to Manganous Ion










Permangate reacts with 8 Hydrogen Ion to form Manganous Ion plus Four water Molecules

R

eduction has taken place!
Four Covalent Bonds in the Permangate Ion are broken when attacked by eight Hydrogen Ions to form Four Water Molecules, but the metallic ion, Manganese, gains 5 electrons from the accompanying oxudation to establish the manganese central atom as the Manganese II (Manganous) 2+ ion.