CHM 1020 Path 4 Chapter 9 Study Pack Part 1
Chapter 9: Chemical Equations
A..Basic Reaction Symbols- Answers
A1.Classifying Chemical Reactions- Answers
B. Balancing Chemical Equations Answers
B1.Predicting Single Replacement Products Answers
B2.Predict Double Replacement Answers
B3 Neutralization/Gas Forming Reactions Answers
Conceptual
Chemistry Chapter 9 Video Links
Chapter
9: How Chemicals React
9.1 Chemical
Reactions Are Represented
by Chemical Equations
9.2 Counting
Atoms and Molecules By Mass
9.3 Converting
Between Grams and Moles
9.4 Chemical
Reactions Can Be Exothermic
or Endothermic
9.5 Chemical
Reactions Are Driven By Entropy
9.6 Chemical
Reactions Can Be Slow or Fast
9.7 Catalysts
Speed Up the Destruction
of Stratospheric Ozone
Evidence for Chemical Reactions
There are four observations that indicate a chemical reaction is taking place:
1. A gas is produced.
Gas may be observed in many ways in a reaction from light fizzing to heavy bubbling.
2. An insoluble solid is produced in a solution.
a. A substance dissolves in water to give an aqueous solution.
b. If we add two aqueous solutions together, we may observe the production of a solid substance.
c. The insoluble solid formed is called a precipitate
3. A permanent color change is observed.
a. Many chemical reactions involve a permanent color change.
b. A change in color indicates that a new substance has been formed
4. An energy change is observed
a. A reaction that releases heat is an exothermic reaction.
b. A reaction that absorbs heat is an endothermic reaction.
c. Examples of a heat energy change in a chemical reaction are heat and light being given off.
Path 4 Chapter 9 Study Packet
In Chapter Four we studied the composition of an atom. In Chapter 3 & 5 we made compounds. Now for Chapter 9 we finally should be able to react these compounds in chemical reactions (or chemical change). The basic symbiology of a chemical reaction is explained in Section 9.1
What are reactants? What are products. What does the arrow between mean? How do we indicate the phase of the chemical? Look at Table 8.1 below summarizes the symbols of a chemical reaction.
Path 4 Chapter 9 Study Packet
Path 4 Chapter 9 Study Packet
Chapter 9 Part A Basic Stoichiometry Definitions
Fill in the following with the symbols used in chemical equations which has the stated translation or meaning(s):
_________1. Produces, yields, gives
_________2. Reacts with, added to, plus
_________ and _________ 3. Solid substance or precipitate forms
_________and _________4. Gaseous substance formed
_________5. Liquid Substance
________5a. Water or aqueous solution
_________6. Reversible Reaction
_________7. No Reaction
8. Show the symbol for heat:__________
9. How would you show a catalyst in a chemical reaction where A plus B forms products D and E, but is catalyzed by substance C
A + B à D + E
10. Define Catalyst (See Section 7.2 page 191)
Path 4 Chapter 9 Study Packet
To start let’s look at 4 five types of reactions: Combination, Decomposition, Single Replacement, Double Replacement, and Neutralization reactions are introduced..
There is a third type of double replacement (Metathesis or Ion Exchange):
Gas Forming Reactions.
When predicting the products of a double replacement reaction, sometimes one of the products instantly decomposes.
If H2CO3 is a predicted product in ion exchange, it is written as
CO2 and H2O.
For example:
Na2CO3 (aq) + HCl (aq) à [H2CO3](aq) + NaCl (aq)
Should be written:
Na2CO3 (aq) + HCl (aq) à CO2(g) + H2O (l) + NaCl (aq)
Two other products which are shown differently:
[NH4OH] à NH3 + H2O
[H2SO3 ] à SO2 + H2O
Path 4 Chapter 9 Study Packet
In chapter 12, there is a seventh type of chemical reaction:
Combustion – a substance burns in the presence of oxygen. Combustion of a compound that contains C and H (or C, H, and O) produces carbon dioxide gas and water.
CH2O(l) + O2(g) → CO2(g) + H2O(l)
The general type of combustion problem looks like this:
CxHy [(l) or (g)] + O2 (g) à CO2 (g) + H2O (g)
Or
CxHyOz[(s) or (l) or (g)] + O2 (g) à CO2 (g) + H2O (g)
The chemical reaction for the combustion of gasoline:
C8H18 (l) + O2 (g) à CO2 (g) + H2O (g)
Octane oxygen gas carbon dioxide water
Path 4 Chapter 9 Study Packet
Chapter 9 Part A1: Classification of Chemical Reactions
Classify Each of the following (unbalanced) chemical reactions as:
______1. Fe + FeCl3 à FeCl2
____2. HCl + Mg(OH)2 à MgCl2 + HOH
_____3. Mg + HNO3 à Mg(NO3)2 + H2
_____4. H2 + N2 à NH3
____5. NaHCO3 + HCl à NaCl + CO2 + H2O
____6. Ca(NO3)2 + K3PO4 à Ca3(PO4)2 + KNO3
____7. KClO3 à KCl + O2
____8. Na + H2O à NaOH + H2
9. Write a chemical equation for solid cadmium hydrogen carbonate decomposing to yield solid cadmium carbonate, water, and carbon dioxide gas:
10. Write a chemical equation for the reaction of aqueous solutions of potassium chromate and calcium sulfate to give the precipitate calcium chromate and aqueous potassium sulfate.
Path 4 Chapter 9 Study Packet
Path 4 Chapter 9 Study Packet
Writing Chemical Reactions
11. Write a chemical equation or solid sodium hydrogen carbonate decomposing to yield solid cadmium carbonate, water, and carbon dioxide gas:
12. Write a chemical equation for the reaction of aqueous solutions of potassium chromate and lead(II) nitrate to give the precipitate lead(II) chromate and aqueous potassium nitrate.
Rules and Suggestions for Balancing Equations
1) The same # and type of atom must be present on each side of the equation.
2) Balancing is accomplished by adding coefficients. NEVER change the subscripts.
3) Coefficients must be in the smallest whole # ratio.
4) Balancing is done by trial and error.
5) Usually Balance H’s and O’s last or an element that appears in more than one place of either side of the reaction .
6) Balance polyatomic ions as one unit in Ion Exchange reactions.
Path 4 Chapter 9 Study Packet
Path 4 Chapter 9 Study Packet
Example of balancing an Equation:
Chapter 9-Part B Balancing Chemical Equations
Balance the following chemical equations (write the chemical formulas in #10 then balance):
1. Fe + FeCl3 à FeCl2
2. Al + O2 à Al2O3
3. Na2CO3 + C + N2 à NaCN + CO
4. FeS + O2 à Fe2O3 + SO2
5. IBr + NH3 à NI3 + NH4Br
6. Cl2 + HOH à HCl + HClO
7. AgNO3 à AgNO2 + O2
8. HClO4 + P4O10 à H3PO4 + Cl2O7
9. HCl + Mg(OH)2 à MgCl2 + HOH
10. Sodium hydroxide + Hydrochloric acid à sodium chloride + water
You may check your work using the online chemical equation balancer at:
http://people.emich.edu/bramsay1/ccc-release/chem.html
M-5i Study Packet
Path 4 Chapter 9 Study Packet
Path 4 Chapter 9 Study Packet
Path 4 Chapter 9 Study Packet
If you were to (H2O) in the activity series like an acid is shown as (H), where would you put it? Show below:
Given the following Activity Series:
Li > K > Ba > Sr > Ca > Na > Mg > Al >
Mn > Zn > Fe > Cd > Co > Ni > Sn >
Pb > (H) > Cu > Ag > Hg > Au
The rule to follow is a single replacement reaction takes place only if the metal or (H) is more active than the metal or (H) it is replacing. Li will react with everything, while Hg will replace only gold. And poor gold does not react with any of the cations of metals. Therefore gold is found pure in nature, while the very active metals such as potassium and sodium are never found pure in nature, but are found as minerals (ionic compounds).
Will Mg metal react with Nitric Acid?
Yes
(Mg has a great reactivity then [H] in the series)
Mg (s) + 2 HNO3 (aq) → Mg(NO3)2 (aq) + H2 (g)
Will Copper react with Nitric Acid? no
(Cu is below [H] in the activity series)
Cu (s) + HNO3 (aq) → no reaction
Given the following Active Metals:
Li > K > Ba > Sr > Ca > Na> (H2O)
The six very active metals are so reactive they will replace one of the two hydrogens in water and form alkaline hydroxides as products. Hydrogen gas will bubble out of the solution. See some of the above movies for demonstrations.
Will Sodium react with water? yes
(Na is one of the six active metals above)
2 Na(s) + 2 HOH (l) → 2 NaOH (aq) + H2 (g)
Path 4 Chapter 9 Study Packet
Part B1 Single Replacement Reactions
Given the following Activity Series:
Li > K > Ba > Sr > Ca > Na > Mg > Al > Mn > Zn > Fe > Cd > Co > Ni >
Sn > Pb > (H) > Cu > Ag > Hg > Au
Given the following Active Metals:
Li > K > Ba > Sr > Ca > Na
Complete the products of the following reactions, then balance the equation (If no reaction write NR):
1. Cu (s) + Al(NO3)3 (aq) à
2. Al (s) + Cu(NO3)2 (aq) à
3. Au (s) + H2SO4 (aq) à
4. Ca (s) + H2O (l) à
5. Mn (s) + H2O (l) à
Path 4 Chapter 9 Study Packet
Part B2 Double Replacement Reactions
Given the following Solubility Rules for Ionic Compounds:
Compounds containing the following ions are generally soluble in water:
1. Alkali metal ions and ammonium ions, Li+ , Na+ , K+ , NH4+
2. Acetate ion, C2H3O2-
3. Nitrate ion, NO3-
4. Halide ions (X), Cl- , Br- , I- (AgX, Hg2X2 , and PbX2 are insoluble exceptions)
5. Sulfate ion, SO4 2- (SrSO4, BaSO4 , and PbSO4 are insoluble exceptions)
Compounds containing the following ions are generally insoluble in water:
6. Carbonate ion,CO32- (see rule 1 exceptions which are soluble)
7. Chromate ion CrO42- (see rule 1 exceptions which are soluble)
8. Phosphate ion PO43- (see rule 1 exceptions which are soluble)
9. Sulfide ion, S2- (CaS, SrS, BaS, and rule 1 exceptions are soluble in water)
10. Hydroxide ion, OH- [ Ca(OH)2 , Sr(OH)2 , Ba(OH)2 , and rule 1 exceptions are soluble)
Complete and balance the following reactions using the above solubility table (write no reaction or NR if both products are soluble or a covalent compounds is not formed)
1. AlCl3 (aq) + K2CO3 (aq) à
2. NiSO4 (aq) + Li3PO4 (aq) à
3. NaCl (aq) + AgNO3 (aq) à
4. H2SO4 (aq) + NaOH (aq) à
5. H3PO4 (aq) + Ba(OH)2 (aq) à
Video:
http://www.brightstorm.com/science/chemistry/chemical-reactions/double-replacement-reactions/
http://www.youtube.com/watch?v=7hVKb4ROjZw
http://www.youtube.com/watch?v=_oixjNeKtxs
http://www.youtube.com/watch?v=IMfNi_C2DTg
http://www.youtube.com/watch?v=2tIutF6-wn4
Path 4 Chapter 9 Study Packet
Part B3 Double Replacement Reaction:
Neutralization/Gas Forming Reactions
Complete and balance the following precipitation reactions using the above solubility table
(write no reaction if both products are soluble or a covalent compounds is not formed)
1. Mg(OH)2 (s) + H2SO4 (aq) à
2. H3PO4 (aq) + KOH (aq) à
3. NH4NO3 (aq) + Ba(OH)2 (aq) à
4. HBr (aq) + Pb(CO3)2 (aq) à
5. LiOH (aq) + H3PO4 (aq) à
6. Na2CO3 (aq) + HCl (aq) à
Video:
http://www.youtube.com/watch?v=gtcE8TosEq4
Note
for Chapter 9 Part B3:
Neutralization ion Exchange Reaction:
1. When an acid reacts with a base, salt plus water are the products
Gas Forming Ion Exchange Reactions:
2. When either H2SO3; H2CO3 or NH4OH is formed as a product it immediately
decomposes thus demonstrating a gas forming reaction.
3. Most books do not show either H2CO3 or NH4OH as products, just the
decomposed products of the gases and water in the answer.
If H2CO3 is a predicted product in ion exchange, it is written as
CO2 and H2O.
For example:
Na2CO3 (aq) + HCl (aq) à [H2CO3](aq) + NaCl (aq)
Should be written:
Na2CO3 (aq) + HCl (aq) à CO2(g) + H2O (l) + NaCl (aq)
Two other products which are shown differently:
[NH4OH] à NH3 + H2O
[H2SO3 ] à SO2 + H2O