Project
8: Building Molecules: Dot Structure Expert 10 points
Objective: To Build the dot structures (or
stick/dot structures) of 40 Molecules
Assignment:
The student is to draw the dot or stick molecular structures
of 37 compounds and three elements. This packet is to be submitted hard copy by
last class meeting or electronically by last day of the term.
The Seven
page dot structure data packet may be access at:
http://www.fscj.me/chm1020/Projects/Project8BuildingMolecules/ DotStructureDataPage.htm
Download
WORD .doc file dot structure packet:
http://www.fscj.me/chm1020/Projects/Project8BuildingMolecules/DotStructureDataPage.doc
Ethylene Molecule
Dot
Structure Stick
Structure
CHM 1020 Text
Reference:
Suchocki
5th : Chapter 6 Section 6.5 Pages 173-177
CHM 1020 Video Reference:
Section 6.5 Covalent
Bonds Result from a Sharing of Electrons (Four Videos)
a. Sharing Electrons Video
#CO605Na (3:42 Minutes) http://bcove.me/neinvkxu
b. Covalent Bond Formation Video #CO605Nb (3:38 Minutes) http://bcove.me/93x3tys9
c. Water, Ammonia, and Methane Video #CO605Nc (5:10 Minutes) http://bcove.me/zmosl2wy
d. Multiple Covalent Bonds Video #CO605Nd (4:21 Minutes) http://bcove.me/5jh8hmus
In Section 6.5 our author does not
list a process for drawing dot structures of molecules as in most text. He discusses
what a single, double, and triple covalent bond is.
He states that a covalent bond consist
of the sharing of one electron from each atom to make the bond. There is also
what is called a coordinate covalent bond, where one atom provides both
electrons to a shared pair.
He also discusses what a lone pair of
electron is (or an unshared pair of electrons). He says that they do not have
to be shown. For this project you have show the all the lone pairs.
He also favors the stick/dot method
for drawing the structures. The following is an excellent table which shows you
the variations on many nonmetals showing bonding via the octet rule. (Rule of 8).
A nonmetal, when bonding with another
nonmetal, should
have eight total electrons including the atoms original outer surface (valence)
electrons plus the electrons provided by the bonded atom. There are few exceptions:
1. Hydrogen follows the rule of two. (see table below)
2. Beryllium follows the rule of four.
3. Boron follows the rule of six (see table below)
The
table leaves out some of the nitrogen (phosphorus, arsenic) variations in the
rule of 8. Nitrogen has three bonds and a lone pair. There could be a double,
single, and lone pair as a second variation. Nitrogen could also have a triple
covalent bond and a lone pair as a third variation.
Most
organic molecules follow the octet rule as carbon always has four bonds, never
a lone pair (except carbon monoxide). We can us the octet rule for over 99% of the of the molecular structures.
However,
most published books use the Mathematical method to determine the covalent
bonding structures and sometimes even though the octet rule can be used to
explain the structure. Sometimes structures of 10, 12, 14 or 16 electrons are around
a single atom. For this course we will use the octet rule, the duet rule for
hydrogen and the rule of six for Boron to keep it simple.
The
mathematical process is shown at the end of this document,
we will use your instructor’s rule of 8 method as follows:
Your
instructor has paper atoms that which you may cutout and use to make your
molecules for the assignment:
Chapter
6: Paper Atoms |
Dot
Structures of Nonmetal Atoms and Ions |
Dot Structures of Atoms (paper atoms): |
Dot/Stick Structures of Atoms (paper atoms): |
Your Instructor’s
Method for Drawing Dot Structures
The following is a modification of the mathematical approach**, where the
octet rule is mainly used via seven steps: (**
mathematical Approach is shown after the instructor’s method)
Never hook oxygen to oxygen except
in peroxides, O2, O3(ozone).
a. Never have an unshared pair or lone pair of electrons on a carbon atom (except carbon monoxide, CO).
b. These are two dimensional structures, so there are many variations of the answer shown on the web site.
c.
Never have more than two bonds to any oxygen
(except CO). If you place hydrogen to an oxygen, then
oxygen HAS to attach to another element by a single bond, never a double bond.
d. If you look carefully at the Dot
Structure Data Page Packet you will find links to the answers.
e. Most of the
molecules that you will draw on the Dot Structure Data pages may be practiced
with the drag and drop molecule building web site. Access the menu at the
following:
http://www.lsua.us/chem1001/dragdrop/menu.html
f. St. Olaf’s College has an interactive construct Lewis Dot Structure web site:
http://www.stolaf.edu/depts/chemistry/courses/toolkits/125/js/lewis/
g. Using
the Flash Player/plug in Lincoln-Sudbury Regional High School in Sudbury, Ma
has
the
following Interactive Web
Site to draw molecules:
http://chemsite.lsrhs.net/bonding/images/lewis%20dot%20tutorial.swf
h. A
high School teacher on Long Island, Mr. Kent, has Interactive chemistry web
pages.
The
following will allow you to construct dot structures of some of the molecules
in this
assignment:
http://www.kentchemistry.com/links/bonding/covalentlewisdot.htm
i. Some answer
pages to check your work: Page 1 Page 3 Page 5 Page 7 Page 9
Drawing
Dot Structures of Molecules via the Mathematical Method (Kotz
5th ):
1.
Decide on the central atom
(usually not oxygen or hydrogen). The central atom is
usually the one with the lowest electron affinity. In formaldehyde, CH2O,
the central atom is carbon.
2.
Determine the total number
of valence electrons in the molecules or the ion. In a neutral molecule this number will be the sum of the valence
electrons of each atom. For a negative ion add the charge to this total number.
For a positive ion subtract the positive charge from this total number. For CH2O:
C=4, H=1(x2) , O=6 this would be 4+2+6 = 12 total valence electrons.
3.
Take this total number of
electrons and divide by two to determine the number of electron pairs. For CH2O: 12/2 = 6 electron
pairs
4.
Place one pair of electrons
between each pair of bonded atoms to form a single bond. You can either show a pair of dots, or draw a single stick
between the two atoms to represent the single covalent bond
5.
Use any remaining pairs as
lone pairs around each atom (except hydrogen) so that each atom is surrounded
by eight electrons. (There is never a lone
pair on a carbon except in Carbon monoxide)
6.
If the central atom has
fewer than eight electrons at this point, move one or more of the lone pairs on
the terminal atoms in a position intermediate between the center and the
terminal atom to form
multiple bonds. (As a general rule double
or triple bonds are formed when both atoms are from the following nonmetals: C,
N, O, S. That is, bonds such as C=C, C=N, C=O, S=O will be encountered
frequently.
Table 9.5 from Kotz displays common oxoacids and
their anions:
Summary of Bishop’s Seven Steps to
Draw Lewis Dot Structures:
Another Table from Hill 12th
From McMurray 5th
Stick Benzene’s Structure: